This study aimed to develop a flexible carbon fiber/oxide layer coating composite with improved electrical properties for use in electronic devices. For this, lead titanate zirconate, cerium-doped lead titanate zirconate, and yttrium-doped lead titanate zirconate were grown on carbon fibers via microwaves-assisted hydrothermal synthesis. The performed synthesis presented advantages when compared to conventional routes used in nanoparticles obtention since it allows the morphological control even at low temperatures. Carbon fiber was selected as substrates due to their thermal stability, excellent mechanical properties, chemical characteristics that allow the creation of functional groups on their surface, and good microwave radiation absorption. The composites were investigated by X-ray diffraction, spectroscopy Raman, and field emission scanning electron microscopy. The electrochemical evaluations were made by four-point probe method, cyclic voltammetry, and electrochemical impedance spectroscopy. The syntheses were successful and the carbon fiber coated with lead zirconate titanate had promissory results, with a boost in the electrical conductivity and better capacitance behavior when compared to the undoped carbon fiber, showing to be a good alternative for applications in electrical devices.