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American Chemical Society, Journal of Physical Chemistry B (Soft Condensed Matter and Biophysical Chemistry), 34(108), p. 13047-13051, 2004

DOI: 10.1021/jp040382l

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Marcus theory for outer-sphere heterogeneous electron transfer: Predicting electron-transfer rates for quinones

Journal article published in 2004 by Nv Rees, Ad Clegg, Ov Klymenko ORCID, Barry A. Coles, Rg Compton
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

Steady-state voltammetry is used to measure the heterogeneous electron-transfer rates for the reduction of quinones to determine the dependence of k0 on molecular size, according to Marcus theory. This dependence is then used to predict the electron-transfer rate constants of related quinones, and the predictions are compared to experimental measurements.