Published in
Royal Society of Chemistry, RSC Advances, 11(8), p. 5670-5677, 2018
DOI: 10.1039/c7ra13587d
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Iminoxyl radicalsvs. tert-butylperoxyl radical in competitive oxidative C–O coupling with β-dicarbonyl compounds. Oxime ether formation prevails over Kharasch peroxidation
Journal article published in 2018 by
I. B. Krylov,
S. A. Paveliev,
N. S. Shumakova,
M. A. Syroeshkin,
B. N. Shelimov,
G. I. Nikishin,
A. O. Terent'ev 
This paper is made freely available by the publisher.
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Abstract
The Kharasch peroxidation system Cu(ii)cat./t-BuOOH, the source oft-BuOO˙ radicals, can be switched to generate iminoxyl radicals by adding various oximes.