International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 9(68), p. o2700-o2701, 2012
DOI: 10.1107/s1600536812034691
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The asymmetric unit of the title compound, C4H5N7, comprises two independent but virtually superimposable molecules. Each molecule is planar with the dihedral angles between the five-membered rings being 2.8 (3) and 2.1 (3)°. The crystal structure is formed by an extensive network of relatively strong N—H⋯N hydrogen-bond interactions. Individual molecules are arranged into supramolecular zigzag chains running parallel to [001] by way of the strongest N—H⋯N interactions. Adjacent chains are interconnected by rather long (D⋯A distances range from ca 3.00 to 3.03 Å) but highly directional (interaction angles above ca 173°) hydrogen bonds forming a supramolecular layer in the bc plane.