AbstractFor the last few decades, researchers have been intrigued by multipolar ordering phenomena and related quantum phase transitions in heavy-fermion Kondo systems. However, a criticality induced by substitution level (x), temperature (T), or magnetic field (B) is poorly understood even in the prototypical material, Ce_1−x La _x B₆, despite a large collection of experimental results is available. In this work, we present T–B, x–T, and x–B phase diagrams of Ce_1−x La _x B₆ (B || [110]). These are completed by investigating heat capacity, magnetocaloric effect (MCE), and elastic neutron scattering. A drastic increase of the Sommerfeld coefficient γ₀, which is estimated from the heat capacity down to 0.05 K, is observed with increasing x. The precise T–B phase diagram including a high-entropy region is derived from the MCE analysis in which a knowledge beyond the equilibrium thermodynamics is involved. Finally, the x–B phase diagram at T = 0, which supports the existence of a quantum critical point at x > 0.75, is obtained by the same analysis. A detailed interpretation of phase diagrams strongly indicates positive correlation between the fluctuating multipoles and the effective electron mass.