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American Chemical Society, Organic Letters, 7(4), p. 1205-1208, 2002

DOI: 10.1021/ol025649i

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Reversing the Stereoselectivity of the Intermolecular Pauson−Khand Reaction: Formation ofendo-Fused Norbornadiene Adducts

Journal article published in 2002 by Ramon Rios, Miquel A. Pericàs ORCID, Albert Moyano, Miguel A. Maestro, José Mahía
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

[reaction: see text] An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.