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The Electrochemical Oxidation of N,N-Diethyl-p-Phenylenediamine in DMF and Analytical Applications. Part I: Mechanistic Study

Journal article published in 2003 by Oleksiy V. Klymenko ORCID, Debora Giovanelli, Nathan S. Lawrence, Neil V. Rees, Li Jiang, Timothy G. J. Jones, Richard G. Compton
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

The electrochemical oxidation of N,N-diethyl-p-phenylenediamine in dimethylformamide has been studied at platinum and gold microdisk electrodes of various radii between 6.7 and 66 μm. The voltammetric responses revealed two electrochemically reversible waves the second of which becomes larger at higher concentrations and bigger electrode radii. The voltammetric signals have been modelled and the electrochemical oxidation reaction is not inconsistent with an ECrevECE reaction. Kinetic parameters are reported.