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Fe/Ge catalyzed carbon nanotube growth on HfO/sub 2/ for nano-sensor applications

Journal article published in 2009 by T. Uchino, G. N. Ayre, D. C. Smith, J. L. Hutchison, C. H. de Groot, P. Ashburn
This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

A carbon nanotube (CNT) growth process on HfO/sub 2/ is reported for the first time for application in nano-sensors. The process uses a combination of Ge nanoparticles and ferric nitrate dispersion and achieves an increase in CNT density from 0.15 to 6.2 mu m length/ mu m/sup 2/ compared with the use of ferric nitrate dispersion alone. The growth process is validated by the fabrication of back-gate CNT field-effect transistors (CNTFETs) using Al source/drain (S/D) contacts and a H/sub 2/ anneal at 400 degrees C. The transistors exhibit p-FET behavior with an I/sub on//I/sub off/ ratio of 10/sup 5/ and a steep sub-threshold slope of 130 mV/dec. These results are rather surprising, as earlier research in the literature on CNTFETs with Al S/D electrodes showed n-FET behavior. The p-FET behavior is shown to be due to the H/sub 2/ anneal, which we ascribe to the smaller electron affinity of hydrogenised CNTs. Measurements of the temperature dependence of the drain current show low Schottky barrier height Al S/D contacts after a H/sub 2/ anneal, which tends to confirm this explanation.