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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 5(19), p. 3523-3531

DOI: 10.1039/c6cp08227k

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Crystallization kinetics of cerium oxide nanoparticles formed by spontaneous, room-temperature hydrolysis of cerium(iv) ammonium nitrate in light and heavy water

Journal article published in 2017 by Natasha W. Pettinger, Robert E. A. Williams, Jinquan Chen ORCID, Bern Kohler ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Ceria nanocrystals form tenfold more slowly in D2O vs. H2O, revealing a rate-determining proton transfer reaction and a non-classical crystallization mechanism.