Published in

American Association for the Advancement of Science, Science, 6424(363), p. 265-270, 2019

DOI: 10.1126/science.aau5701

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A Eu3+-Eu2+ ion redox shuttle imparts operational durability to Pb-I perovskite solar cells

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A redox road to recovery Device longevity is a key issue for organic-inorganic perovskite solar cells. Encapsulation can limit degradation arising from reactions with oxygen and water, but light, electric-field, and thermal stresses can lead to metastable elemental lead and halide atom defects. Wang et al. show that for the lead-iodine system, the introduction of the rare earth europium ion pair Eu 3+ -Eu 2+ can shuttle electrons and recover lead and iodine ions (Pb 2+ and I ). Devices incorporating this redox shuttle maintained more than 90% of their initial power conversion efficiencies under various aging conditions. Science , this issue p. 265