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Royal Society of Chemistry, Dalton Transactions, 17(46), p. 5540-5545, 2017

DOI: 10.1039/c6dt04570g

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Uranium rhodium bonding in heterometallic complexes

Journal article published in 2017 by J. A. Hlina, J. A. L. Wells, Jason B. Love ORCID, James R. Pankhurst ORCID, P. L. Arnold ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The UIV–RhIintermetallic distances in the U2Rh2complex (left, 2.7601(5) Å) and URh complex (right, 2.7630(5) Å) are very short and almost identical in the solid state even though solution electrochemistry suggests very different metal-based reduction processes.