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Royal Society of Chemistry, Chemical Communications, 96(52), p. 13897-13900

DOI: 10.1039/c6cc08008a

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From an equilibrium based MOF adsorbent to a kinetic selective carbon molecular sieve for paraffin/iso-paraffin separation

Journal article published in 2016 by Baiyan Li, Youssef Belmabkhout, Yiming Zhang, Prashant M. Bhatt, Hongming He, Daliang Zhang, Yu Han ORCID, Mohamed Eddaoudi, Jason A. Perman, Shengqian Ma ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

We unveil a unique kinetic driven separation material for selectively removing linear paraffins from iso-paraffins via a molecular sieving mechanism. Subsequent carbonization and thermal treatment of CD-MOF-2, the cyclodextrin metal-organic framework, afforded a carbon molecular sieve with a uniform and reduced pore size of ca. 5.0 Å, and it exhibited highly selective kinetic separation of n-butane and n-pentane from iso-butane and iso-pentane, respectively. © The Royal Society of Chemistry.