Decarboxylative Aminomethylation of Aryl- and Vinylsulfonates through Combined Nickel- and Photoredox-Catalyzed Cross-Coupling
Journal article published in 2016 by
Lulu Fan,
Jiaqi Jia,
Hong Hou,
Quentin Lefebvre 
,
Magnus Rueping
,
Magnus Rueping
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Abstract
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C−O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.