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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 4(67), p. m431-m431, 2011

DOI: 10.1107/s160053681100849x

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meso-[5,10,15,20-Tetra­kis(4-cyano­phen­yl)porphyrinato]zinc

Journal article published in 2011 by Shuai Dong, Jianzhuang Jiang
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

In the title compound, [Zn(C(48)H(24)N(8))], the coordination environment of the Zn(2+) ion (site symmetry [Formula: see text]) is octa-hedral, with four indole N atoms forming the equatorial plane and the axial positions being occupied by N atoms from the cyanide groups of neighbouring molecules. In the crystal, adjacent mol-ecules are assembled into a two-dimensional supra-molecular framework parallel to ([Formula: see text]01) via the coodination bonding. Topology analysis reveals this compound to be a (4,4)-connected network.