Published in
Royal Society of Chemistry, Dalton Transactions, 7(45), p. 3158-3162, 2016
DOI: 10.1039/c5dt04317d
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Covalency hinders AnO 2 (H 2 O) + → AnO(OH) 2 + isomerisation (An = Pa–Pu)
Journal article published in 2016 by
Nikolas Kaltsoyannis
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Abstract
Computational analysis of the electronic structures of AnO2(H2O)+ (An = Pa–Pu) demonstrates that isomerisation to AnO(OH)2+ is least favoured for the system with the most covalent An–Oyl bond.