Published in

International Union of Crystallography, IUCrData, 4(1), 2016

DOI: 10.1107/s2414314616006118

Links

Tools

Export citation

Search in Google Scholar

4,4,5,5-Tetramethyl-2-[( Z )-1-(3-methylphenoxy)hex-1-en-2-yl]-1,3,2-dioxaborolane

Journal article published in 2016 by Kai-Xiao Li, Xiao-Juan Wang
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The title compound, C19H29BO3, was prepared by the reaction of 1-(hex-1-yn-1-yloxy)-3-methylbenzene in tetrahydrofuran with 4,4,5,5-tetramethyl-1,3,2-dioxaborolane under a nitrogen atmosphere. In the molecule, the butyl group adopts an extended conformation, with a torsion angle of 179.52 (19)°. The dioxaborolane ring has a twisted conformation on the C—C bond, and its mean plane is inclined to the 3-methylphenyl ring by 44.79 (19)°. In the crystal, there are no significant intermolecular interactions present.