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Royal Society of Chemistry, Dalton Transactions, 6(44), p. 2588-2596

DOI: 10.1039/c4dt02362e

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Mixed sandwich thorium complexes incorporating bis(tri-isopropylsilyl)cyclooctatetraenyl and pentamethylcyclopentadienyl ligands: synthesis, structure and reactivity

Journal article published in 2015 by Zoë E. Button, Jessica A. Higgins, Markéta Suvova, F. Geoffrey N. Cloke, S. Mark Roe
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis of thorium complexes of the type Th(COTTIPS2)Cp*X (X = Cl, I, CH2Ph, H) and their reactivity towards CO2, including reductive coupling to form an oxalate complex, are reported.