Published in

Cambridge University Press, Annals of Glaciology, (20), p. 440-447, 1994

DOI: 10.3189/1994aog20-1-440-447

Cambridge University Press, Annals of Glaciology, (20), p. 440-447

DOI: 10.1017/s0260305500016827

Cambridge University Press, Annals of Glaciology, 1(20), p. 440-447

DOI: 10.3189/172756494794587159

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Spatial variability of the major chemistry of the Antarctic ice sheet

Journal article published in 1994 by R. Mulvaney ORCID, E. W. Wolff
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Data provided by SHERPA/RoMEO

Abstract

A compilation of reliable data for sodium, nitrate, chloride and sulphate has been made. NO3 concentrations arc remarkably consistent across Antarctica, though there appears to be some correlation with altitude and accumulation rate. Post-depositional loss of NO3- is important at low-accumulation sites. Cl concentration (either measured directly or calculated from Na+ via the sea salt ratio) decreases with distance from the coast, though the decline is less rapid if the coastal topography is not steep or mountainous. Excess sulphate (xsSO42) concentration (here calculated from normal sea-salt ratios with Na+ or Cl) also declines with distance from the coast, though less quickly than Cl-. Fractionation of sea-salt ions makes the calculation of SO42- uncertain.