Published in

Wiley, Angewandte Chemie, 47(126), p. 13022-13025, 2014

DOI: 10.1002/ange.201407997

Wiley, Angewandte Chemie International Edition, 47(53), p. 12808-12811

DOI: 10.1002/anie.201407997

Links

Tools

Export citation

Search in Google Scholar

A Carbene-Rich but Carbonyl-Poor [Ir6(IMe)8(CO)2H14]2+Polyhydride Cluster as a Deactivation Product from Catalytic Glycerol Dehydrogenation

Journal article published in 2014 by Jesús Campos, Liam S. Sharninghausen ORCID, Robert H. Crabtree, David Balcells ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Upload
Orange circle
Postprint: archiving restricted
Upload
Red circle
Published version: archiving forbidden
Policy details
Data provided by SHERPA/RoMEO

Abstract

The title cluster, a deactivation product in the catalytic dehydrogenation of glycerol, was characterized by XRD, DFT calculations, HRMS, FTIR spectroscopy, and NMR spectroscopy. Experimental/computational studies located the 14 H ligands, and all 1H and 13C{1H} NMR resonances were assigned. The structure contains an unprecedented Ir6H14 core with two CO and eight IMe ligands.