Published in
Royal Society of Chemistry, Organic and Biomolecular Chemistry, 4(14), p. 1421-1427, 2016
DOI: 10.1039/c5ob02128f
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Reaction mechanisms in ionic liquids: the kinetics and mechanism of the reaction of O,O-diethyl (2,4-dinitrophenyl) phosphate triester with secondary alicyclic amines
Journal article published in 2016 by
Paulina Pavez 
,
Daniela Millán,
Javiera Morales,
Mabel Rojas,
Daniel Céspedes,
José G. Santos
,
Daniela Millán,
Javiera Morales,
Mabel Rojas,
Daniel Céspedes,
José G. Santos
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Abstract
In the title reaction, the ionic liquids used stabilized the zwitterionic pentacoordinate intermediate (P±), leading to a change in the mechanism from concerted to stepwise.