Published in
Royal Society of Chemistry, Dalton Transactions, 42(43), p. 15693-15696, 2014
DOI: 10.1039/c4dt02078b
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Enhanced association for C<sub>70</sub> over C<sub>60</sub> with a metal complex with corannulene derivate ligands
Journal article published in 2014 by
Celedonio M. Álvarez 
,
Luis A. García-Escudero,
Raúl García-Rodríguez,
Jose M. Martín-Álvarez ,
Daniel Miguel,
Víctor M. Rayón
,
Luis A. García-Escudero,
Raúl García-Rodríguez,
Jose M. Martín-Álvarez ,
Daniel Miguel,
Víctor M. Rayón
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Abstract
The geometry imposed by the coordination sphere around the metal, together with the choice of the “arms” can be advantageously used to build corannulene-based molecular tweezers, which show great affinities for C60 and C70, as revealed by NMR titration experiments.