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Elsevier, Nano Energy, (15), p. 709-718, 2015

DOI: 10.1016/j.nanoen.2015.05.032

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Melting and solidification of bismuth antimony telluride under a high magnetic field: A new route to high thermoelectric performance

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Imposing an intensity variable high static magnetic field during traditional melting-solidification (MS) method has been used as a new method to prepare p-type bismuth antimony telluride thermoelectric materials in this work. On this basis, we present a systematic study of the nucleation, crystal orientation, microstructure, electrical and thermal transport properties of the obtained alloy ingots solidified under different magnetic field intensities. A c-axis alignment of bismuth antimony telluride in the direction perpendicular to the magnetic field, formation of BSTII nanorods, and a simultaneous optimization of the electrical and thermal transport properties has been observed. Consequently, an enhanced ZTmax=1.71 at 323 K has been achieved in a polycrystalline Bi0.5Sb1.5Te3 sample solidified under a 2T magnetic field.