Published in
Elsevier, Journal of Molecular Catalysis A: Chemical, 1-2(165), p. 135-140
DOI: 10.1016/s1381-1169(00)00370-8
Links
Tools
Homogeneous and heterogeneous catalytic oxidation of benzylic and secondary alcohols with a metal dioxygenato complex in the presence of 2-methylpropanal and dioxygen
Journal article published in 2001 by
Stefania Roberta Cicco 
,
Mario Latronico,
Piero Mastrorilli,
Gian Paolo Suranna,
Cosimo Francesco Nobile
,
Mario Latronico,
Piero Mastrorilli,
Gian Paolo Suranna,
Cosimo Francesco Nobile
This paper is available in a repository.
Full text: Download
Postprint:
archiving forbidden
Published version:
archiving forbidden
Data provided by 
Abstract
The oxidation of benzylic and secondary alcohols under homogeneous conditions was achieved at 40°C using molecular oxygen as the oxidant in the presence of excess 2-methylpropanal and catalytic amount of Co(acac)2. The oxidation reactions were also carried out with a heterogeneous analogue of Co(acac)2 revealing that the supported cobalt polymer acts as an active and reusable catalyst.