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Wiley, Angewandte Chemie International Edition, 42(49), p. 7702-7705, 2010

DOI: 10.1002/anie.201002320

Wiley, Angewandte Chemie, 42(122), p. 7868-7871

DOI: 10.1002/ange.201002320

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Terbium Polyoxometalate Organic Complexes: Correlation of Structure with Luminescence Properties

Journal article published in 2010 by Chris Ritchie, Evan G. Moore ORCID, Manfred Speldrich, Paul Kögerler, Colette Boskovic
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Light up the POMs: A luminescent lanthanoid complex with polyoxometalate (POM) and organic ligands has been structurally characterized (see picture). Comparison of this octanuclear TbIII complex of 2-picolinate and tungstoarsenate ligands with a dinuclear relative reveals the role of the organic ligands as chromophores, identifies the luminescent Tb centers, and determines the relationship between POM coordination mode and luminescence quenching.