Published in
Royal Society of Chemistry, Chemical Communications, 53(50), p. 7014-7016
DOI: 10.1039/c4cc02601b
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Selective P4 activation by an organometallic nickel(i) radical: formation of a dinuclear nickel(ii) tetraphosphide and related di- and trichalcogenides
Journal article published in 2014 by
Stefan Pelties,
Dirk Herrmann,
Bas de Bruin 
,
František Hartl,
Robert Wolf
,
František Hartl,
Robert Wolf
This paper is made freely available by the publisher.
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Abstract
The reaction of the 17e nickel(i) radical [CpNi(IDipp)] (1, IDipp = 1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene) with P4 results in a nickel tetraphosphide [{CpNi(IDipp)}2(μ-η(1):η(1)-P4)] with a butterfly-P4(2-) ligand; related chalcogenides [{CpNi(IDipp)}2(μ-E2)] (E = S, Se, Te) and [{CpNi(IDipp)}2(μ-E3)] (E = S, Se) are formed with S8, Se∞ and Te∞.