Published in
Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 13(3), p. 6739-6741, 2015
DOI: 10.1039/c4ta07196d
Links
Tools
Advancing polymers of intrinsic microporosity by mechanochemistry
This paper is available in a repository.
Full text: Download
Published version:
archiving forbidden
Data provided by 
Abstract
Herein, we report a fast (15 min) and solvent-free mechanochemical approach to polymers of intrinsic microporosity(PIMs) with high molecular mass and low polydipersity by solid grinding. The enhanced reaction efficiency results from the instantaneous frictional heating and continuously exposing active sites within those solid reactants.