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Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 17(3), p. 9216-9222, 2015

DOI: 10.1039/c4ta06126h

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Investigation on regeneration kinetics at perovskite/oxide interface with scanning electrochemical microscopy

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This paper is available in a repository.

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Abstract

Scanning electrochemical microscopy (SECM) is a powerful technique for quantitative and qualitative investigation of interfacial charge transfer processes. This work presents an SECM investigation on the regeneration kinetics of an organo-metal halide perovskite (CH3NH3PbI3) sensitized onto various semiconductor oxide nanocrystals, including n-type titanium dioxide and p-type nickel oxide. We found for the first time that the regeneration rate constant, and absorption cross section of CH3NH3PbI3 are significantly higher than the conventional sensitizers.