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American Chemical Society, Organometallics, 10(17), p. 1919-1921, 1998

DOI: 10.1021/om9800748

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Reactions of Group 4 Metal Cyclopentadienyl Trifluorides with a Trimeric Iminoalane

This paper is available in a repository.
This paper is available in a repository.

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Abstract

Reaction of CpMF3 (M = Ti, Zr) with [MeAlN(2,6-iPr2C6H3)]3 leads to fluorine−nitrogen exchange and the formation of isostructural adamantane-like cages. This reaction proceeds with activation of metal−fluorine bonds and can be regarded as a new route to aluminum-containing mixed group 4 amidofluorides.