American Chemical Society, Journal of the American Chemical Society, 44(130), p. 14448-14449, 2008
DOI: 10.1021/ja807035j
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We have demonstrated that the rod segments with lateral dendritic chains self-assemble into unique stepped strips in which the rods are aligned parallel to the strip long axis. This unique organization of the rod segments arises from a balance between the energetic gain of a parallel arrangement of the rods and the resulting entropic penalty associated with stretching of the lateral flexible chains.