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American Chemical Society, Journal of the American Chemical Society, 44(130), p. 14448-14449, 2008

DOI: 10.1021/ja807035j

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Stepped Strips from Self-Organization of Oligo(p-phenylene) Rods with Lateral Dendritic Chains

This paper is available in a repository.
This paper is available in a repository.

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Abstract

We have demonstrated that the rod segments with lateral dendritic chains self-assemble into unique stepped strips in which the rods are aligned parallel to the strip long axis. This unique organization of the rod segments arises from a balance between the energetic gain of a parallel arrangement of the rods and the resulting entropic penalty associated with stretching of the lateral flexible chains.