The Electrochemical Society, ECS Transactions, 24(28), p. 77-94, 2010
DOI: 10.1149/1.3496423
The Electrochemical Society, Journal of The Electrochemical Society, 12(157), p. C452
DOI: 10.1149/1.3499564
The Electrochemical Society, Journal of The Electrochemical Society, 12(157), p. C458
DOI: 10.1149/1.3499565
Full text: Unavailable
CPE behavior may be attributed to the distribution of physical properties in films, in the direction normal to the electrode surface. Numerical simulations were used to show that, under assumption that the dielectric constant is independent of position, a normal power-law distribution of local resistivity is consistent with the Constant-Phase Element (CPE). An analytic expression for the impedance corresponding to a power-law distribution of resistivity was developed and used to establish a relationship between parameters for the CPE and physical properties of the film. The resulting impedance response was compared to that obtained from the Young resistivity distribution.