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Published in

The Electrochemical Society, ECS Transactions, 24(28), p. 77-94, 2010

DOI: 10.1149/1.3496423

The Electrochemical Society, Journal of The Electrochemical Society, 12(157), p. C452

DOI: 10.1149/1.3499564

The Electrochemical Society, Journal of The Electrochemical Society, 12(157), p. C458

DOI: 10.1149/1.3499565

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Constant-Phase-Element Behavior Caused by Resistivity Distributions in Films

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

CPE behavior may be attributed to the distribution of physical properties in films, in the direction normal to the electrode surface. Numerical simulations were used to show that, under assumption that the dielectric constant is independent of position, a normal power-law distribution of local resistivity is consistent with the Constant-Phase Element (CPE). An analytic expression for the impedance corresponding to a power-law distribution of resistivity was developed and used to establish a relationship between parameters for the CPE and physical properties of the film. The resulting impedance response was compared to that obtained from the Young resistivity distribution.