American Physical Society, Physical Review A, 3(88)
DOI: 10.1103/physreva.88.032506
Full text: Unavailable
Using the core-mass approach, we have generated a vibrational-mass surface for the triatomic H3+. The coordinate-dependent masses account for the off-resonance nonadiabatic coupling and permit a very accurate determination of the rovibrational states using a single potential energy surface. The new, high-precision measurements of 12 rovibrational transitions in the ν2 bending fundamental of H3+ by Wu et al. [ Phys. Rev. A 88 032507 (2013)] are used to scale this surface empirically and to derive state-dependent vibrational and rotational masses that reproduce the experimental transition energies to 10−3 cm−1. Rotational term values for J≤10 are presented for the two lowest vibrational states and equivalent transitions in D3+ considered.