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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 2(64), p. m369-m370, 2008

DOI: 10.1107/s1600536808001153

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Cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate

Journal article published in 2008 by Torben Birk, Jesper Bendix ORCID, Högni Weihe
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation.