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Facultad de Humanidades y Ciencias de la Educación, Synthesis: Journal of Synthetic Organic Chemistry, 02(45), p. 246-250

DOI: 10.1055/s-0032-1317895

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Boron Trifluoride as an Efficient Catalyst for the Selective Synthesis of Tricyclic Monoperoxides from β,δ-Triketones and H2O2

Journal article published in 2012 by Alexander Terent’ev ORCID, Ivan A. Yaremenko, Vera A. Vil, Vera Vil’, Valery M. Dembitsky, Gennady I. Nikishin
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Boron trifluoride was found to serve as an efficient catalyst for the reaction of beta,delta-triketones with H2O2 producing tricyclic monoperoxides in yields from 48-93%. BF3 acts simultaneously as a catalyst and co-solvent. The synthesis can be scaled up to tens of grams. The resulting peroxides can be easily isolated from the reaction mixture by column chromatography.