Published in

Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 47(2), p. 20280-20287, 2014

DOI: 10.1039/c4ta03620d

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Hybrid acrylic/CeO2 nanocomposites using hydrophilic spherical and high aspect ratio CeO2 nanoparticles

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

A dispersion of CeO2 nanoparticles and nanorods stabilized with nitrilotriacetic acid (NTA) and 4,4’-Azobis(4-cyanovaleric acid) (V-501) initiator has been used to initiate the emulsion polymerization of acrylic monomers, yielding stable hybrid CeO2 nanoparticles-nanorods/polyacrylate latexes for the first time. Films casted from these hybrid latexes are transparent due to the very homogenous distribution of the polymer compatibilized CeO2. Furthermore, it has been proven that the UV-Vis absorption capacity of the hybrid latexes is enhanced with the incorporation of the nanorods.