Published in
Royal Society of Chemistry, Dalton Transactions, 35, p. 7223
DOI: 10.1039/b906730b
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Trinuclear copper(I) complexes with triscarbene ligands: Catalysis of C-N and C-C coupling reactions
Journal article published in 2009 by
Andrea Biffis,
Cristina Tubaro,
Elena Scattolin,
Marino Basato,
Grazia Papini,
Carlo Santini,
Eleuterio Alvarez 
,
Salvador Conejero
,
Salvador Conejero
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Abstract
Novel synthetic routes for the preparation of trinuclear copper(I) complexes with triscarbene ligands are presented, which yield higher purity products than the one previously described. The first crystal structure of one of these complexes is reported and confirms the expected structure. The trinuclear complexes proved to be efficient catalysts of Ullmann-type reactions as well as of the Sonogashira reaction.