Wiley, Angewandte Chemie International Edition, 34(50), p. 7807-7810, 2011
Wiley, Angewandte Chemie, 34(123), p. 7953-7956, 2011
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Molecular spinning tops: Five halogen-bonded isotopologues of the CF 3Cl-H 2O complex have been assigned by Fourier-transform microwave spectroscopy. All complexes are symmetric-top systems with evenly spaced bonds. The free internal rotation, relative stability, and structure of these complexes were determined (see picture; Ψ, θ, and φ: angles, a and b: axes of the monomer, and A: axis of the complex).