Published in
Royal Society of Chemistry, Chemical Communications, 18, p. 2074
DOI: 10.1039/b406494a
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Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene
Journal article published in 2004 by
Vladimir V. Burlakov,
Perdita Arndt,
Wolfgang Baumann,
Anke Spannenberg,
Uwe Rosenthal,
Pattiyil Parameswaran 
,
Eluvathingal D. Jemmis
,
Eluvathingal D. Jemmis
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Abstract
The 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene (bis-titanocene-mu-(Z)-1,2,3-butatriene complex)3 is formed starting from [Cp2Ti(eta2-Me3SiC2SiMe3)] by in situ generated titanocene and 1,4-dichlorobut-2-yne via the 1-titanacyclobut-3-yne (2).