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American Chemical Society, Inorganic Chemistry, 5(40), p. 1065-1066, 2001

DOI: 10.1021/ic001137t

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Crystal Structure Determination of a (μ-Amido)(μ-hydroxo)(μ-superoxo)dicobalt(III) Complex from the Werner Collection

This paper was not found in any repository; the policy of its publisher is unknown or unclear.
This paper was not found in any repository; the policy of its publisher is unknown or unclear.

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Abstract

By use of crystals from the Werner collection at the University of Zurich, the X-ray structure of a (mu -amido)(mu -hydroxo)(mu -superoxo)dicobalt(III) salt, probably synthesized around 1909, was determined. This complex is apparently the first dimetallic species with three bridging ligands of such a composition. The O-O bond distance of 1.340(4) Angstrom is consistent with. coordinated superoxo anion, and the two cobalt atoms are 2.776(1) Angstrom apart.