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Royal Society of Chemistry, Physical Chemistry Chemical Physics, 17(17), p. 11586-11592, 2015

DOI: 10.1039/c5cp01307k

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Defect-dependent colossal negative thermal expansion in UiO-66(Hf) metal-organic framework

Journal article published in 2015 by Matthew J. Cliffe ORCID, Joshua A. Hill ORCID, Claire A. Murray, Francois-Xavier Coudert ORCID, Andrew L. Goodwin
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Thermally densified UiO-66(Hf) shows the strongest reported isotropic negative thermal expansion (NTE) in a metal–organic framework. Incorporation of defects allows for tuning of the magnitude of both the densification and the NTE.