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Royal Society of Chemistry, Chemical Communications, 23, p. 2445-2447, 2006

DOI: 10.1039/b602675c

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Condensed phase behaviour of ionic liquid–benzene mixtures: congruent melting of a [emim][NTf2]·C6H6inclusion crystal

This paper is available in a repository.
This paper is available in a repository.

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Abstract

The solid-liquid phase diagram of the (1-ethyl-3-methylimidazolium bis{(trifluoromethyl) sulfonyl} amide + benzene) system was determined and allowed us to identify and characterize an equimolar inclusion compound, [emim][NTf2].C6H6, with a congruent melting temperature: this type of behaviour, reported here for the first time, together with the X-ray structure of the inclusion compound lays emphasis upon the interactions that are responsible for the existence of liquid clathrates at higher benzene concentrations.