Published in

Royal Society of Chemistry, Journal of Materials Chemistry A: materials for energy and sustainability, 3(2), p. 581-584, 2014

DOI: 10.1039/c3ta13691d

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Highly soluble alkoxide magnesium salts for rechargeable magnesium batteries

This paper is available in a repository.
This paper is available in a repository.

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Abstract

A unique class of air-stable and non-pyrophoric magnesium electrolytes has been developed based on alkoxide magnesium compounds. The crystals obtained from this class of electrolytes exhibit a unique structure of tri-magnesium cluster, [Mg3Cl3(OR)2(THF)6]+ [(THF)MgCl3]−. High reversible capacities and good rate capabilities have been obtained in Mg–Mo6S8 batteries using these new electrolytes at both 20 and 50 °C.