Published in
Elsevier, Tetrahedron, 27(56), p. 4765-4768
DOI: 10.1016/s0040-4020(00)00383-5
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Synergistic effect in bimetallic Ni-Al clusters. Application to efficient catalytic reductive dehalogenation of polychlorinated arenes
Journal article published in 2000 by
Fabien Massicot,
Raphaël Schneider 
,
Yves Fort,
Sandra Illy-Cherrey,
Olivier Tillement
,
Yves Fort,
Sandra Illy-Cherrey,
Olivier Tillement
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Abstract
Subnanometric Ni–Al clusters, in situ prepared by reduction of equimolar amounts of Ni(OAc)2 and Al(Acac)3 induced by alkoxide activated sodium hydride, exhibit a high catalytic activity for efficient reductive dehalogenation of aliphatic and aromatic halides and polychlorinated arenes.