Royal Society of Chemistry, Analytical Methods, 9(6), p. 2837-2847, 2014
DOI: 10.1039/c3ay41312h
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Trace metals are fundamental components of various biochemical reactions for phytoplankton. They serve as micronutrients and therefore play a key role in marine biogeochemical cycles. International programs such as GEOTRACES require fast, sensitive and reliable methods for the simultaneous analysis of multiple trace elements in seawater. This paper reports the development of a simplified, automated, low cost, portable, off-line extraction method with high sample throughput. The extraction uses the chelating resin Nobias-chelate PA1 offering an extraction factor of 18 from 27 mL of seawater. This solid phase extraction has been coupled to Sector Field-Inductively Coupled Plasma-Mass Spectrometry (SF-ICP-MS) for analysing dissolved manganese Mn (dMn), cobalt (dCo), nickel (dNi), copper (dCu), cadmium (dCd) and lead (dPb). An optimum pH of 6.2 was selected allowing quantitative recovery of most elements of interest, offering stable Cu and minimum Molybdenum (Mo) recoveries, limiting interferences of Cd de