Published in
Elsevier, Tetrahedron Letters, 16(41), p. 2999-3002
DOI: 10.1016/s0040-4039(00)00291-4
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Aza-bowls: synthesis and molecular structure of triaza-[3]-peristylane
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Abstract
A one-pot synthesis of the first aza-bowl, [3]-aza-[3]- eristylane system, from bullvalene is described. The molecular structure of this novel entity has been probed by X-ray crystallography and theoretical calculations.