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Elsevier, Journal of Alloys and Compounds, (536), p. S507-S510

DOI: 10.1016/j.jallcom.2012.01.012

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Phase stability and magnetic properties of a new cobalt(II) coordination polymer based on 2-carboxyethylphosphonate and 1,10′-phenanthroline

Journal article published in 2012 by E. Fernández Zapico, J. Montejo Bernardo, R. D’Vries, J. R. García, S. García Granda, J. Rodríguez Fernández ORCID, I. de Pedro, J. A. Blanco
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This paper is available in a repository.

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Abstract

Co-2(HO3PCH2CH2COO)(2)(C12H8N2)(2) has been synthesized from [Co-2(HO3PCH2CH2COO)(2)(C12H8N2)(2)(mu-OH2)](H2O) by thermal treatment (350 degrees C) under inert atmosphere (N-2). The transformation between the initial compound to a red-pink crystalline solid is mediated by an intermediate blue amorphous material. Co-2(HO3PCH2CH2COO)(2)(C12H8N2)(2) is stable in air until 440 degrees C, showing some trends of being magnetically ordered below 2 K. (c) 2012 Elsevier B.V. All rights reserved.