Published in
Royal Society of Chemistry, Chemical Communications, 48(51), p. 9817-9820, 2015
DOI: 10.1039/c5cc01428j
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A Stable Fluorinated and Alkylated Lithium Malonatoborate Salt for Lithium Ion Battery Application
Journal article published in 2015 by
Shun Wan,
Xueguang Jiang 
,
Bingkun Guo,
Sheng Dai,
Xiao-Guang Sun,
John B. Goodenough
,
Bingkun Guo,
Sheng Dai,
Xiao-Guang Sun,
John B. Goodenough
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Abstract
A new fluorinated and alkylated lithium malonatoborate salt, lithium bis(2-methyl-2-fluoromalonato)borate (LiBMFMB), has been synthesized for lithium ion battery application. The new salt based electrolyte, 0.8 M LiBMFMB in ethylene carbonate (EC) and ethyl methyl carbonate (EMC) (1:2 by wt.), exhibits good cycling stability and rate capability in LiNi0.5Mn1.5O4 and graphite based half-cells.