Taylor and Francis Group, Liquid Crystals, 6-7(37), p. 961-968, 2010
DOI: 10.1080/02678292.2010.481902
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A simple method to determine the translational order parameter of a smectic liquid crystal is presented. It is based on a measurement of the absolute intensity of the first−order layer reflection from an unaligned (powder) sample using small−angle neutron scattering. The Lorentz factor and molecular form factor are used to derive the order parameter from the intensity. The method is demonstrated for 4−octyl−4'−cyanobiphenyl (8CB), using two different isotopomers which give a consistent translational order parameter value of 0.5 in the smectic A phase.