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Springer, Russian Journal of Organic Chemistry, 9(49), p. 1307-1312, 2013

DOI: 10.1134/s107042801309011x

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Acylation of 2-Arylamino-3-chloro-5,8-dihydroxy-1,4-naphthoquinones

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Abstract

2-Arylamino-3-chloro-5,8-dihydroxy-1,4-naphthoquinones reacted with acetic anhydride and benzoyl chloride in pyridine to give in succession the corresponding O-acyl derivatives at both hydroxy groups. The primary acylation products were 8-acyloxy-2-arylamino-3-chloro-5-hydroxy-1,4-naphthoquinones.