Elsevier, Journal of Organometallic Chemistry, 16(693), p. 2818
DOI: 10.1016/j.jorganchem.2008.05.036
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Three palladium(II) complexes and four platinum(II) complexes having general formula CpFe{1,2-C(5)H(3)(PPh(2))(CH(2)SR)}MCl(2) (M = Pd, R = Ph, Et and tBu; M = Pt, R = Ph, Et, tBu and Cy) have been synthesized by reaction of the corresponding CpFe{1,2-C(5)H(3)(PPh(2))(CH(2)SR)} ligands with PdCl(2)(CH(3)CN)(2) or PtCl(2)(CH(3)CN)(2). These complexes have been fully characterized in solution and in solid state. In all cases, monomeric square planar complexes were obtained as pure diastereoisomers.