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Elsevier, Journal of Organometallic Chemistry, 16(693), p. 2818

DOI: 10.1016/j.jorganchem.2008.05.036

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Palladium and platinum complexes with planar chiral 1,2-disubstituted ferrocenes containing phosphine and thioether donor groups [Journal of Organometallic Chemistry 693 (2008) 1469–1477]

Journal article published in 2008 by Raluca Malacea, Lucie Routaboul, Eric Manoury, Jean-Claude Daran, Rinaldo Poli ORCID
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This paper is available in a repository.

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Abstract

Three palladium(II) complexes and four platinum(II) complexes having general formula CpFe{1,2-C(5)H(3)(PPh(2))(CH(2)SR)}MCl(2) (M = Pd, R = Ph, Et and tBu; M = Pt, R = Ph, Et, tBu and Cy) have been synthesized by reaction of the corresponding CpFe{1,2-C(5)H(3)(PPh(2))(CH(2)SR)} ligands with PdCl(2)(CH(3)CN)(2) or PtCl(2)(CH(3)CN)(2). These complexes have been fully characterized in solution and in solid state. In all cases, monomeric square planar complexes were obtained as pure diastereoisomers.