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American Chemical Society, Journal of Organic Chemistry, 11(67), p. 3975-3978, 2002

DOI: 10.1021/jo025657c

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Intrazeolite Photooxidations of Electron-Poor Alkenes

Journal article published in 2002 by Edward L. Clennan, Jakub P. Sram, Andrea Pace ORCID, Katie Vincer, Sophia White
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The inability of the intrazeolite environment to influence the regiochemistry of addition of singlet oxygen to electron-poor olefins is reported. This divergent behavior with respect to electron-rich alkenes is rationalized with a multicomplexation model that emphasizes the importance of intrazeolite substrate-cation binding.